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A statistical mechanical study of current spikes due to phase transitions at electrode-electrolyte interfaces - MaRDI portal

A statistical mechanical study of current spikes due to phase transitions at electrode-electrolyte interfaces (Q2465492)

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A statistical mechanical study of current spikes due to phase transitions at electrode-electrolyte interfaces
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    A statistical mechanical study of current spikes due to phase transitions at electrode-electrolyte interfaces (English)
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    4 January 2008
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    The authors continue their statistical mechanical study of voltammogram spikes. They present a theory from which voltammogram spikes corresponding to first-order phase transitions can be obtained. Moreover the theory can be applied to experiment and show that macroscopic properties of a voltammogram spike determine the strength of microscopic interactions in a lattice gas that one may use to model the associated deposition process.
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    voltammogram
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    first-oder phase transition
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    lattice gas
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