Phase transition upon solidification from a liquid state (Q2746947)

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scientific article; zbMATH DE number 1656882
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Phase transition upon solidification from a liquid state
scientific article; zbMATH DE number 1656882

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    11 October 2001
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    crystallization
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    equilibrium model
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    nonequilibrium model
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    Phase transition upon solidification from a liquid state (English)
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    A criterion that allows one to predict a priori a mechanism (equilibrium or nonequilibrium) according to which the phase transition upon solidification of a melt from a liquid state will occur is obtained. The fundamental possibility of experimental determination of the kinetic constant and the energy of activation is shown on the basis of the phase-transition criterion obtained and the solution of the problem of sequential nonequilibrium crystallization.
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