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Specifics of thermodynamic description of nanocrystals

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Publication:6135211

DOI10.1140/EPJB/E2013-31088-2zbMATH Open1515.82147arXiv1301.3310OpenAlexW3098925255MaRDI QIDQ6135211

Author name not available (Why is that?)

Publication date: 26 July 2023

Published in: (Search for Journal in Brave)

Abstract: A method of statistical description of thermodynamic properties of nanocrystals is developed. It is established that size-dependent quantization of vibrational modes results in formation of excess pressure of the phonon gas acting outwards the crystal. Based on the concept of the phonon gas pressure, size dependence of thermodynamic properties of nanocrystals was described, and size influence on a shift of a phase transformation temperature was explained.


Full work available at URL: https://arxiv.org/abs/1301.3310



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