On the symmetry of the quantum-mechanical particle in a cubic box

Publication date: 18 October 2013

Abstract: In this paper we show that the point-group (geometrical) symmetry is insufficient to account for the degeneracy of the energy levels of the particle in a cubic box. The discrepancy is due to hidden (dynamical symmetry). We obtain the operators that commute with the Hamiltonian one and connect eigenfunctions of different symmetries. We also show that the addition of a suitable potential inside the box breaks the dynamical symmetry but preserves the geometrical one.The resulting degeneracy is that predicted by point-group symmetry.

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