Coulomb interaction in electrolyte solutions
The goal of the study is to find corrections to the Debye-Huckel law. The model supposes displacements of ions around the central ion due to the Brownian motion. If the averaged displacement radius is assumed equal for all ions, the free energy formula after expansion over the concentration level will feature a third term, which is parametrically dependent on the displacement value.
scientific article; zbMATH DE number 6183618
scientific article